Ethyl acetate
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“Ethyl acetate can dissolve up to three percent water and has a solubility of eight percent in water at room temperature. At elevated temperature its solubility in water is higher.”
See:
http://pubs.acs.org/doi/abs/10.1021/ja01103a501
Most data that I have shows lower solubility in water lower at elevated temperature. However, my data are (organic compound in EA)/water. So, maybe not exactly pure EA/water.
Thanks.